Synthesis, Structure and Physical Properties of A Novel 2D Cd(TI) Coordination Polymer Involving 4-Thiopyridine Based on in situ Formation from 4,4'-Dithiodipyridine

摘要

Exploratory synthesis of coordination polymer remains intensely active not only owing to their diverse topology and intriguing structures but also because of these materials' capabilities in industrially relevant applications such as ion-exchange, heterogeneous catalysts, optical devices, magnets, and gas storage.1"6 It is well known that the organic ligand is the key factor that influences the construction of coordination polymer. Recently, the in situ ligand synthesis as a new approach to prepare coordination polymers are of great interest. In situ hydrothermal reactions usually not only provide products that are inaccessible or not easily obtainable by conventional methods, but also help discover the mechanism of some kinds of organic reactions.