Spectrophotometric and Electrochemical Study of Cu~(2+)-Selective Azocalix[4]arene Bearing p-Carboxyl group

Tae Hyun Kim; Jong Seung Kim; Hasuck Kim

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Spectrophotometric and Electrochemical Study of Cu~(2+)-Selective Azocalix[4]arene Bearing p-Carboxyl group

机译：Cu〜（2 +）-选择性偶氮杂[4]芳烃对羧基的分光光度法和电化学研究

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The spectrophotometric and electrochemical properties of tetraazo(p-carboxy)phenylcalix[4]arene (p-CAC) in the presence of various metal ions were investigated by UV/Vis spectroscopy and voltammetry in CH3CN. p-CAC showed selective color changes to Cu~(2+) over other metal ions from light orange to colorless, in accordance with hypsochromic shift in UV/Vis spectra. Voltammetric measurements also showed high selectivity for Cu~(2+).

机译：通过在CH3CN中的UV / Vis光谱和伏安法研究了在各种金属离子存在下四偶氮（对羧基）苯基杯杯[4]芳烃（p-CAC）的分光光度和电化学性质。根据紫外/可见光谱中的变色位移，p-CAC对其他金属离子的选择性颜色变化为Cu〜（2+），从浅橙色变为无色。伏安测量也显示出对Cu〜（2+）的高选择性。

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《Bulletin of the Korean Chemical Society》 |2013年第11期|共4页
作者
Tae Hyun Kim; Jong Seung Kim; Hasuck Kim;
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正文语种 eng
中图分类化学;
关键词
Azocalixarene; Copper ion; Colorimetry; Voltammetry;

机译：氮杂芳烃铜离子比色法伏安法;

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1. Spectrophotometric and Electrochemical Study of Cu~(2+)-Selective Azocalix[4]arene Bearing p-Carboxyl group [J] . Tae Hyun Kim, Jong Seung Kim, Hasuck Kim Bulletin of the Korean Chemical Society . 2013,第11期

机译：Cu〜（2 +）-选择性偶氮杂[4]芳烃对羧基的分光光度法和电化学研究
2. Spectrophotometric and electrochemical behavior of a novel azocalix[4]arene derivative as a highly selective chromogenic chemosensor for Cr~(+3) [J] . Haluk Bingol, Erdal Kocabas, Erhan Zor, Electrochimica Acta . 2011,第5期

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Spectrophotometric and Electrochemical Study of Cu~(2+)-Selective Azocalix[4]arene Bearing p-Carboxyl group

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