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首页> 外文期刊>Bulletin of the Korean Chemical Society >The Empirical Enskog-Like Approximation of Shear Viscosity in the Penetrable-Sphere Model
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The Empirical Enskog-Like Approximation of Shear Viscosity in the Penetrable-Sphere Model

机译:可穿透球体模型中的剪切粘度的经验类比逼近

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The so-called penetrable-sphere (PS) interaction potential is defined as u~(PS) (r) = {ε, r < σ/0, r > σ (1) where σ is the diameter penetrable sphere, and ε (> 0) is the strength of the repulsive energy barrier between two overlapping spheres when they penetrate each other. The PS system simply reduces to the hard-sphere (HS) model in the zero-temperature limit, i.e., T*(≡ k_BT/ε) → 0, or ε*(≡ k_BT/ε) → 0, or ε*(≡ ε/k_BT) → ∞, where k_B is the Boltzmann constant, and T the temperature. In the opposite high-temperature limit T* → ∞, or the high-penetrability limit ε* → 0, the PS system becomes a collisionless ideal gas. For the PS system, in principle, the overlapping penetrability allows any possible value of the nominal packing fraction φ (= (π/6)ρ*), where ρ*(=Nσ3/V) is the reduced number density. Note that the maximum packing fraction in the pure HS system is 2 π/6 (≈ 0.7405) from the face-centered cubic structure.
机译:所谓的可穿透球体(PS)相互作用势定义为u〜(PS)(r)= {ε,r <σ/ 0,r>σ(1)其中σ是直径可穿透球体,ε( > 0)是两个重叠球体相互穿透时的排斥能垒的强度。 PS系统简单地在零温度极限下简化为硬球(HS)模型,即T *(≡k_BT /ε)→0,或ε*(≡k_BT /ε)→0,或ε*( εε/ k_BT)→∞,其中k_B是玻尔兹曼常数,T是温度。在相反的高温极限T *→∞或高渗透性极限ε*→0下,PS系统成为无碰撞的理想气体。对于PS系统,原则上,重叠渗透性允许标称堆积分数φ(=(π/ 6)ρ*)的任何可能值,其中ρ*(=Nσ3/ V)是减少的数量密度。请注意,纯HS系统的最大填充分数从面心立方结构为2π/ 6(≈0.7405)。

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