Trifluoromethylation of Nonenolizable Carbonyl Compounds with a Stable Piperazino Hemiaminal of Trifluoroacetaldehyde

Thierry Billard; Bernard R.Langlois; Gaelle Blond

首页> 外文期刊>European journal of organic chemistry >Trifluoromethylation of Nonenolizable Carbonyl Compounds with a Stable Piperazino Hemiaminal of Trifluoroacetaldehyde

【24h】

Trifluoromethylation of Nonenolizable Carbonyl Compounds with a Stable Piperazino Hemiaminal of Trifluoroacetaldehyde

机译：稳定的哌嗪子酮的三氟乙醛缩醛缩合不可烯化的羰基化合物的三氟甲基化

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A new stable hemiaminal of fluoral (1) can easily be obtained from teh methyl hemiketal of fluoral and N-benzylpiperazine.This white crystalline compound can be used under basic conditions as an efficient nucleopilic trifluoromethylating reagent towards nonenolizable carbonyl compouns.

机译：从氟的甲基半缩醛和N-苄基哌嗪可以很容易地获得新的稳定的氟（1）缩醛。该白色结晶化合物在碱性条件下可以用作对不可烯化的羰基化合物的有效的核三氟甲基化试剂。

著录项

来源
《European journal of organic chemistry》 |2001年第8期|共5页
作者
Thierry Billard; Bernard R.Langlois; Gaelle Blond;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
nitrogen heterocycles; fluorine; aldehydes; nucleophilic addition; fluoral;

机译：氮杂环;氟;醛;亲核加成;氟;

相似文献

外文文献
中文文献
专利

1. Trifluoromethylation of Nonenolizable Carbonyl Compounds with a Stable Piperazino Hemiaminal of Trifluoroacetaldehyde [J] . Thierry Billard, Bernard R.Langlois, Gaelle Blond European journal of organic chemistry . 2001,第8期

机译：稳定的哌嗪子酮的三氟乙醛缩醛缩合不可烯化的羰基化合物的三氟甲基化
2. Nucleophilic trifluoromethylation of carbonyl compounds: Trifluoroacetaldehyde hydrate as a trifluoromethyl source [J] . Surya Prakash G.K., Zhang Z., Wang F., The Journal of Organic Chemistry . 2013,第7期

机译：羰基化合物的亲核三氟甲基化：三氟乙醛水合物作为三氟甲基源
3. New Stable Reagents for the Nucleophilic Trifluoromethylation. 1. Trifluoromethylation of Carbonyl Compounds with N-Formylmorpholine Derivatives [J] . T. Billard, S. Bruns, B. R. Langlois Organic letters . 2000,第14期

机译：亲核三氟甲基化的新稳定试剂。 1.用N-甲酰基吗啉衍生物对羰基化合物进行三氟甲基化
4. Asymmetric Synthesis of β-Trifluoromethylated β-Amino Carbonyl Compounds Based on the 1,2-Addition to Trifluoroacetaldehyde SAMP- or RAMP-Hydrazones [C] . Kazumasa Funabiki, rnMasashi Nagamori, rnMasaki Matsui, Current fluoroorganic chemistry : New synthetic directions, technologies, materials, and biological applications . 2005

机译：基于三氟乙醛SAMP-或RAMP-y的1,2-加成反应，β-三氟甲基化的β-氨基羰基化合物的不对称合成
5. The trifluoromethylation of aromatic transition metal substrates and antimony(V) compounds. [D] . Muller, Doris Lee. 2002

机译：芳族过渡金属底物和锑（V）化合物的三氟甲基化。
6. Nucleophilic Trifluoromethylation of Carbonyl Compounds: Trifluoroacetaldehyde Hydrate as a Trifluoromethyl Source [O] . G. K. Surya Prakash, Zhe Zhang, Fang Wang, -1

机译：羰基化合物的亲核三氟甲基化：三氟乙醛水合物作为三氟甲基源
7. Nucleophilic Trifluoromethylation of Carbonyl Compounds: Trifluoroacetaldehyde Hydrate as a Trifluoromethyl Source [O] . G. K. Surya Prakash, Zhe Zhang, Fang Wang, 2013

机译：羰基化合物的亲核三氟甲基化：三氟甲醛水合物作为三氟甲基源

Trifluoromethylation of Nonenolizable Carbonyl Compounds with a Stable Piperazino Hemiaminal of Trifluoroacetaldehyde

摘要

著录项

相似文献

相关主题

期刊订阅