Chelated Enolates of Amino acid Esters-New and Efficient Nucleophiles for Isomerization-Free, Stereoselective Palladium-Catalyzed Allylic Substitutions

Uli Kazmaier; Franz L. Zumpe

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Chelated Enolates of Amino acid Esters-New and Efficient Nucleophiles for Isomerization-Free, Stereoselective Palladium-Catalyzed Allylic Substitutions

机译：氨基酸酯的螯合烯醇酸酯-新型和高效的亲核试剂，可无异构化，立体选择性钯催化的烯丙基取代基

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摘要

Chelated amino acid ester enolates were found to be suitable mucleophiles for palladium-catalyzed allylic alkylations.

机译：发现螯合的氨基酸酯烯醇盐是适合钯催化的烯丙基烷基化的亲胶体。

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《European journal of organic chemistry》 |2001年第21期|共10页
作者
Uli Kazmaier; Franz L. Zumpe;
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正文语种 eng
中图分类有机化学;
关键词
Allylic alkylation; Amino acids; Enolates; Isomerization; Palladium;

机译：烯丙基烷基化;氨基酸;烯醇盐;异构化;钯;

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专利

1. Chelated Enolates of Amino acid Esters-New and Efficient Nucleophiles for Isomerization-Free, Stereoselective Palladium-Catalyzed Allylic Substitutions [J] . Uli Kazmaier, Franz L. Zumpe European journal of organic chemistry . 2001,第21期

机译：氨基酸酯的螯合烯醇酸酯-新型和高效的亲核试剂，可无异构化，立体选择性钯催化的烯丙基取代基
2. [(p-Cymene)RuCl_2]_2: An Efficient Catalyst for Highly Regioselective Allylic Alkylations of Chelated Amino Acid Ester Enolates [J] . Anton Bayer, Uli Kazmaier Chemistry: A European journal . 2014,第33期

机译：[（p-Cymene）RuCl_2] _2：螯合氨基酸酯烯醇化物的高区域选择性烯丙基烷基化的高效催化剂
3. [(p-Cymene)RuCl_2]_2: An Efficient Catalyst for Highly Regioselective Allylic Alkylations of Chelated Amino Acid Ester Enolates [J] . Anton Bayer, Uli Kazmaier Chemistry: A European journal . 2014,第33期

机译：[（p-Cymene）RuCl_2] _2：螯合氨基酸酯烯醇化物的高区域选择性烯丙基烷基化的高效催化剂
4. Hydroxyapatite-supported Palladium-catalyzed Allylation of Carbon Nucleophiles with Allylic Carbonates [C] . Yukiko Nakajima, Yoshiro Masuyama Symposium on Organometallic Chemistry . 2007

机译：羟基磷灰石支持的钯催化碳亲核催化烯丙基碳酸酯
5. Molybdenum and palladium catalyzed asymmetric allylic alkylation of prochiral nucleophiles: Enantioselective synthesis of nonnatural alpha-amino acids and of tertiary alpha-hydroxy carboxylic acid derivatives. [D] . Franzini, Maurizio. 2005

机译：钼和钯催化的前手性亲核试剂的不对称烯丙基烷基化：非天然α-氨基酸和叔α-羟基羧酸衍生物的对映选择性合成。
6. Raising the pKa Limit of Soft Nucleophiles in Palladium-Catalyzed Allylic Substitutions. Application of Diarylmethane Pronucleophiles [O] . Sheng-Chun Sha, Jiadi Zhang, Patrick J. Carroll, -1

机译：在钯催化的烯丙基取代基中提高软亲核试剂的pKa限。二芳基甲烷亲核试剂的应用
7. Palladium-Catalyzed Regio- and Stereoselective Cross-Coupling of Vinylethylene Carbonates with Ketimine Esters to Generate (Z)Tri- and Tetra-substituted Allylic Amino Acid Derivatives [O] . -1

机译：钯催化的乙烯基碳酸亚乙烯酯与酮氨基酯的立体选择性交联，以产生（Z）三和四取代的烯丙基氨基酸衍生物

Chelated Enolates of Amino acid Esters-New and Efficient Nucleophiles for Isomerization-Free, Stereoselective Palladium-Catalyzed Allylic Substitutions

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