A New Synthetic Approach Toward (+)-Ambruticin Analogs: Preparation of a C10-C11 cis-Isomer Fragment

Veronique Michelet; Kouacou Adiey; dBruno Bulic; Jean-Pierre Genet; Gilles Dujardin; Sandrine Rossignol; Eric Brown; Loic Toupet

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A New Synthetic Approach Toward (+)-Ambruticin Analogs: Preparation of a C10-C11 cis-Isomer Fragment

机译：（+）-Ambruticin类似物的一种新的合成方法：C10 C11顺式异构体片段的制备。

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摘要

A new methodology has been applied to synthesize an isomer of the west part of (+)-ambruticin based on an efficient asymmetric de novo access to the A unit and sequential stereospecific reactions catalyzed by Pd~o for the construction of the B unit.

机译：基于对A单元的高效不对称从头反应以及由Pdo催化的连续立体有择反应，B结构的构建已经应用了一种新的方法来合成（+）-安布卢奇西部的异构体。

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来源
《European journal of organic chemistry》 |1999年第11期|共8页
作者
Veronique Michelet; Kouacou Adiey; dBruno Bulic; Jean-Pierre Genet; Gilles Dujardin; Sandrine Rossignol; Eric Brown; Loic Toupet;
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正文语种 eng
中图分类有机化学;
关键词
ambruticin; asymmetric synthesis; pyranose; carbohydrates; C-glycosylation; alkylations; palladium;

机译：幕布;不对称合成;吡喃糖;碳水化合物;C-糖基化;烷基化;钯;

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1. A New Synthetic Approach Toward (+)-Ambruticin Analogs: Preparation of a C10-C11 cis-Isomer Fragment [J] . Veronique Michelet, Kouacou Adiey, dBruno Bulic, European journal of organic chemistry . 1999,第11期

机译：（+）-Ambruticin类似物的一种新的合成方法：C10 C11顺式异构体片段的制备。
2. New Aspects in the Stereoselective Ethynylation of β-C-Glycoside Aldehydes. Application to the Synthesis of an Ambruticin Fragment [J] . Veronique Michelet, Kouacou Adiey, Suzelle Tanier, European journal of organic chemistry . 2003,第15期

机译：β-C-糖苷醛的立体选择性乙炔化的新方面。在安布定片段合成中的应用
3. Synthesis of (2S)-4-Methyl- and (2S)-4-Methyl-6-oxo-3,6-dihydro-2H-pyran-2-carbaldehydes as Precursors to C-22-C-27 Fragments of Fijianolides and Their Synthetic Analogs [J] . Mineeva I. V. Russian Journal of Organic Chemistry . 2018,第9期

机译：合成（2S）-4-甲基 - （2S）-4-甲基-6-氧代-3,6-二氢-2H-吡喃-2-碳醛作为Fijianolides的C-22-C-27片段的前体和他们的合成类似物
4. Highly Selective Preparation of 4-Aminocyclohexane Carboxylic Acid from cis-Isomer over Raney Nickel Catalyst [C] . Sandor Gobolos, Zoltan Banka, Zoltan Toth Organic Reactions Catalysis Society Conference . 2007

机译：在Raney镍催化剂上由CIS-ISOMER的4-氨基环己烷羧酸的高度选择性制备
5. A reiterative approach for the synthesis of the C(28)-C(20) fragment of rifamycin S polypropionate chain by the diastereoselective preparation and regioselective cleavage of oxiranes. Efficient and regioselective copper catalyzed alkenyl Grignard cleavage of 1,2-disubstituted epoxides [D] . Rodriguez Reyes, David 2006

机译：一种通过非对映选择性制备和区域选择性裂解环氧乙烷来合成利福霉素S聚丙烯酸酯链的C（28）-C（20）片段的迭代方法。高效和区域选择性铜催化的1,2-二取代环氧化物烯基格利雅裂解
6. Efficacy of Ambruticin Analogs in a Murine Model of Invasive Pulmonary Aspergillosis [O] . Lisa Y. Chiang, Daniele E. Ejzykowicz, Zong-Qiang Tian, 2006

机译：Ambruticin类似物在小鼠侵袭性肺曲霉病模型中的功效
7. Synthetic Studies of Ambruticin: Preparation of the C1-C8 Tetrahydropyran and the C17-C24 Dihydropyran Segments [O] . Luping Liu, Julie L. Wondergem (nee Lukesh), William A. Donaldson 2015

机译：琥珀酸的合成研究：C1-C8四氢吡喃和C17-C24二氢吡喃段的制备
8. SYNTHETIC ATTEMPTS FOR THE PREPARATION OF NITROGEN ANALOGS OF AKLANES AND ALKENES. [R] . zimmer,hans 1965

机译：用于制备aKLaNEs和aLKENEs氮类似物的合成方法。

A New Synthetic Approach Toward (+)-Ambruticin Analogs: Preparation of a C10-C11 cis-Isomer Fragment

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