N-Amino-exo-3,6-epoxy-1,2,3,6-tetrahydrophthalimide as an ActiveAminoaziridinating Agent

摘要

N-Amino-exo-3 , 6 - epoxy- 1 , 2 , 3 , 6 -tetrahydrophthalimide isactive in the oxidative aminoaziridination reaction toward al-kenes substituted with aryl-, alkyl, and electron-withdrawinggroups, providing access to stable derivatives of N-aminoaz-iridine. Yields varied from 19 to 76 %, and trans-substituted alkenes reacted faster and gave better yields than cis-alkenes. No products of self-aziridination were isolated.