Chemorheological analysis of a gelled resol resin curing under non-isothermal conditions by shear strain

摘要

The chemorheological behavior of curing of a resol resin was analyzed under non-isothermal conditions beyond the gelation point. Two heating ramps (0.5 and 1 oC/min) from 0 to 100C were performed. The rheological measurements of the resin were performed using oscillatory shear strain. The obtained profiles for the resin's complex viscosity were applied, after treatment by two calculation methods, to the four- and six-parameter Arrhenius models. These models allow one to establish the viscous flow region of the resin and the kinetic parameters of the material's curing process. The six-parameter Arrhenius model was selected as the best method for modeling of the resin's rheological behavior during its curing process. The viscous-flow activation energies determined for the gelled resol resin curing were 67.1 and 58.3kJ/mol for the 0.5 and 1 oC/min heating rates, respectively. The activation energies of the resin curing process were 41.7 and 67.0kJ/mol for each temperature ramp.