Living radical polymerization of MMA in the presence of piperidino-dithiocarbamate derivatives as photoiniferters [French]

摘要

Radical polymerizations of methyl methacrylate were carried out in the presence of photoiniferters (RDC) containing a piperidino-dithiocarbamate group. The effects of the structure of the RDC on the photopolymerization in the presence or absence of a transfer agent such as tetraethylthiuram disulfide (TD) were investigated. The influence of the presence of a transfer agent (TD) on the living character and the control of the polymerization were also discussed. (C) 1997 Elsevier Science Ltd. [References: 12]