An Unusual 3D Interdigitated Architecture Self-Assembled from Sidearm-Containing 2D Bilayer Motifs with a Cuboidal Framework

摘要

The new complex [Zn(H_2bptc)(bpy)]centre dot 0.5bpdo (1) [H_4bptc = 3,3',4,4'-biphenyltetracarboxylic acid,bpy = 4,4'-bipyridine,and bpdo = 4,4'-bipyridine N,N'-dioxide] has been synthesized and characterized.It exhibits a novel (2D->3D) inter-digitated architecture that is obtained for the first time from the self-assembly of sidearm-containing bilayer motifs with a cuboidal framework,in which each cuboidal box of one bilayer is interdigitated by two arms that belong to two adjacent bilayers.The luminescent properties of 1 are discussed.