Hydrothermal Synthesis of a Two-Dimensional Coordination Polymer [Fe(phen)(#mu#-bta)_1/2]_n (bta = Benzene-1,2,4,5-tetracarboxylate, phen = 1, 10-Phenanthroline)

De-Qing Chu; Ji-Qing Xu; Li-Mei Duan; Tie-Gang Wang; Ao-Qing Tang; Ling Ye

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Hydrothermal Synthesis of a Two-Dimensional Coordination Polymer [Fe(phen)(#mu#-bta)_1/2]_n (bta = Benzene-1,2,4,5-tetracarboxylate, phen = 1, 10-Phenanthroline)

机译：水热合成二维配位聚合物[Fe（phen）（＃mu＃-bta_1 / 2）_n（bta =苯-1,2,4,5-四羧酸酯，phen = 1，10-菲咯啉）

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摘要

A metal-ligand complex [Fe(phen)(#mu#-bta)_1/2]_n (phen = 1,10-phelanthroline; bta = benzene-1,2,4,5-tetracarboxylate ligand) has been hydrothermally synthesized and structurally characterized by single crystal X-ray crystallography, showing that it ossesses a novel, two-dimensional polymeric structure.

机译：已经水热合成了金属-配体配合物[Fe（phen）（＃mu＃-bta）_1 / 2] _n（phen = 1,10-邻苯二酚; bta =苯-1,2,4,5-四羧酸酯配体）通过单晶X射线晶体学表征其结构，表明它具有新颖的二维聚合物结构。

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来源
《European journal of inorganic chemistry》 |2001年第5期|共3页
作者
De-Qing Chu; Ji-Qing Xu; Li-Mei Duan; Tie-Gang Wang; Ao-Qing Tang; Ling Ye;
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正文语种 eng
中图分类无机化学;
关键词
carboxylate ligands; crystal engineering; iron; N ligand; X-ray diffraction; poymers;

机译：羧酸盐配体;晶体工程;铁;N配体;X射线衍射;聚合物;

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1. Hydrothermal Synthesis of a Two-Dimensional Coordination Polymer [Fe(phen)(#mu#-bta)_1/2]_n (bta = Benzene-1,2,4,5-tetracarboxylate, phen = 1, 10-Phenanthroline) [J] . De-Qing Chu, Ji-Qing Xu, Li-Mei Duan, European journal of inorganic chemistry . 2001,第5期

机译：水热合成二维配位聚合物[Fe（phen）（＃mu＃-bta_1 / 2）_n（bta =苯-1,2,4,5-四羧酸酯，phen = 1，10-菲咯啉）
2. Hydrothermal synthesis, structures and properties of coordination polymers based on mu(4)-bridging benzene-1,2,4,5-tetracarboxylate: [Co(Him)2(mu(4)-bta)(1/2)](n) and {[Cu(phen)(mu(4)-bta)(1/2)] center dot H2O}(n) (bta = benzene-1,2,4,5-tetracarboxyl [J] . Zhang LJ., Xu JQ., Shi Z., International Journal of Quantum Chemistry . 2003,第1期

机译：基于mu（4）-桥苯1,2,4,5-四羧酸酯的配位聚合物的水热合成，结构和性能：[Co（Him）2（mu（4）-bta）（1/2）]（ n）和{[Cu（phen）（mu（4）-bta）（1/2）]中心点H2O}（n）（bta =苯-1,2,4,5-四羧基苯
3. Hydrothermal synthesis and crystal structure of a metal-organic coordination polymer with double-helical structure:[Fe(phen)(ipt)]_n (ipt=isophthalate,phen=1,10-phenanthroline) [J] . Yu Hou, Enhong Shen, Shutao Wang, Inorganic Chemistry Communications . 2003,第10期

机译：具有双螺旋结构的金属-有机配位聚合物的水热合成和晶体结构：[Fe（phen）（ipt）] _ n（ipt =间苯二甲酸，phen = 1,10-菲咯啉）
4. Hydrothermal Synthesis and Characterization of the Coordination Polymers with bta =Benzene-1,2,4,5- tetracarboxylate as Bridging Ligand: {Cu(phen)(μ4-bta)1/2· (H2O)}n(phen= 1,10-phenanthroline) [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：以bta =苯-1,2,4,5-四羧酸苯酯为桥联配体的水热合成和表征：{Cu（phen）（μ4-bta）1/2·（H2O）} n（phen = 1,10-菲咯啉
5. Synthesis and Structural Characterization of Mercury(II) Coordination Polymers Based on 1,2,4,5-Tetra(Isopropylthio) Benzene Ligand [D] . Selby-Karney, Troy. 2018

机译：1,2,4,5-四（异丙硫基）苯配体的汞（II）配位聚合物的合成与结构表征
6. Two-dimensional hydrogen-bonded polymers in the crystal structures of the ammonium salts of phenoxyacetic acid (4-fluorophenoxy)acetic acid and (4-chloro-2-methylphenoxy)acetic acid [O] . Graham Smith 2014

机译：苯氧基乙酸（4-氟氧基）乙酸和（4-氯-2-甲基氧基）乙酸的铵盐晶体结构中的二维氢键聚合物
7. Synthesis and Anti-Candida Activity of Cobalt(II) Complexes of Benzene-1,2-Dioxyacetic Acid (bdoaH2). X-Ray Crystal Structures of [Co(bdoa)(H2O)3] ⋅3.5H2O and {[CO(phen)3](bdoa)}2⋅24H2O (phen = 1,10-Phenanthroline) [O] . Geraghty, Majella, McCann, Malachy, Devereux, Michael, 1999

机译：钴（II）配合物的合成及其抗念珠菌活性。苯1,2-二氧乙酸（bdoaH2）。 [Co（bdoa）（H2O）3]的X射线晶体结构 ⋅3.5H2O和{[CO（phen）3]（bdoa）}2⋅24H2O （phen = 1,10-菲咯啉）

Hydrothermal Synthesis of a Two-Dimensional Coordination Polymer [Fe(phen)(#mu#-bta)_1/2]_n (bta = Benzene-1,2,4,5-tetracarboxylate, phen = 1, 10-Phenanthroline)

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