Self-Assembly and Characterization of Grid-Type Copper(I),Silver(I),and Zinc(II)Complexes

摘要

The reactions of ligand L,which comprises two bidentate binding units,with copper(I),silver(I),and zinc(II)lead to the self-assembly of the expected supramolecular architectures 1-3,respectively,of the [2 x 2] grid type,containing four ions in tetrahedral coordination sites.The grid-type structures are assigned on the basis of the spectroscopic data in solution,and confirmed in the solid state in the case of complex 2 by X-ray crystallography.