A rare thermally induced single crystal to single crystal transformation from a 2D chiral coordination polymer to a 3D chiral coordination polymer

摘要

A rare single-crystal to single crystal (SCSC) transformation assisted by hydrogen bonding was induced thermally. A 2D homochiral coordination polymer {[Ni-2(L-tar)(2)(H2O)(2)](H2O)(3)). was irreversibly converted into a 3D homochiral coordination polymer, and the structure was confirmed by Xray crystallography and XRD. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).