Enhancement of Nematic Order and Global Phase Diagram of a Lattice Model for Coupled Nematic Systems

摘要

We use an infinite-range Maier–Saupe model. with two sets of local quadrupolar variables and restricted orientations, to investigate the global phase diagram of a coupled system of two nematic subsystems. The free energy and the equations of state are exactly calculated by standard techniques of statistical mechanics. The nematic–isotropic transition temperature of system A increases with both the interaction energy among mesogens of system B, and the two-subsystem coupling .1. This enhancement of the nematic phase is manifested in a global phase diagram in terms of the interaction parameters and the temperature T. We make some comments on the connections of these results with experimental findings for a system of diluted ferroelectric nanoparticles embedded in a nematic liquid-crystalline environment.