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Removal of heavy metal ions from aqueous solution by zeolite synthesized from fly ash

机译:粉煤灰合成沸石去除水溶液中重金属离子的研究。

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摘要

Zeolite was synthesized from coal fly ash by a fusion method and was used for the removal of heavy metal ions (Pb2+, Cd2+, Cu2+, Ni2+, and Mn2+) in aqueous solutions. Batch method was employed to study the influential parameters such as adsorbent dosage, pH, and coexisting cations. Adsorption isotherms and kinetics studies were carried out in single-heavy and multiheavy metal systems, respectively. The Langmuir isotherm model fitted to the equilibrium data better than the Freundlich model did, and the kinetics of the adsorption were well described by the pseudo-second-order model, except for Cd2+ and Ni2+ ions which were fitted for the pseudo-first-order model in the multiheavy metal system. The maximum adsorption capacity and the distribution coefficients exhibited the same sequence for Pb2+ > Cu2+ > Cd2+ > Ni2+ > Mn2+ in both single- and multiheavy metal systems. In the end, the adsorption capacity of zeolite was tested using industrial wastewaters and the results demonstrated that zeolite could be used as an alternative adsorbent for the removal of heavy metal ions from industrial wastewater.
机译:用熔融法由粉煤灰合成沸石,用于去除水溶液中的重金属离子(Pb2 +,Cd2 +,Cu2 +,Ni2 +和Mn2 +)。采用批处理法研究了影响因素,如吸附剂用量,pH值和共存阳离子。吸附等温线和动力学研究分别在单重金属和多重金属系统中进行。 Langmuir等温线模型比Freundlich模型更适合平衡数据,并且吸附动力学由伪二级模型很好地描述,除了Cd2 +和Ni2 +离子适合伪一级重金属系统中的模型。在单重金属系统和多重金属系统中,Pb2 +> Cu2 +> Cd2 +> Ni2 +> Mn2 +的最大吸附容量和分布系数具有相同的顺序。最后,利用工业废水对沸石的吸附能力进行了测试,结果表明该沸石可作为替代吸附剂用于去除工业废水中的重金属离子。

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