Pt nanowires prepared via a polymer template method: Its promise toward high Pt-loaded electrocatalysts for methanol oxidation

摘要

Platinum nanowires were prepared via a template-synthesis method by electrodeposition of platinum within pores of a track-etched polycarbonate (PCTE) membrane, followed by chemical etching to separate the Pt nanowires from the polymer. The structure and morphology of the Pt nanowires were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM), revealing a polycrystalline phase with nanowire dimension up to 6 μm long and ca. 47 ± 9.8 nm of diameter. The unsupported Pt nanowires showed the better electrochemical mass activities over the methanol electro-oxidation than supported or unsupported Pt nanoparticles under the high Pt content-loaded conditions that is typically required for direct methanol fuel cells. This enhancement could be rationalized by its unique physicochemical and electrical properties arising from the inherent anisotropic one-dimensional (1D) nanostructure, such as charge transfer facilitation by reducing number of particle interfaces and more efficient use of Pt by alleviating fraction of embedded catalysts.