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首页> 外文期刊>Electrochemistry communications >Fabrication of anode-supported Sc _2O _3-stabilized- ZrO _2 electrolyte micro-tubular Solid Oxide Fuel Cell by phase-inversion and dip-coating
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Fabrication of anode-supported Sc _2O _3-stabilized- ZrO _2 electrolyte micro-tubular Solid Oxide Fuel Cell by phase-inversion and dip-coating

机译:通过相转化和浸涂法制备阳极支撑的Sc _2O _3-稳定的ZrO _2电解质微管固体氧化物燃料电池

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摘要

An anode-supported Sc _2O _3-stabilized-ZrO _2 (ScSZ) electrolyte micro-tubular solid oxide fuel cell (MT-SOFC) with a cell configuration of Ni-YSZ|Ni-ScSZ|ScSZ|LSM-ScSZ|LSM has been prepared by a combination of phase-inversion and dip-coating technology. ScSZ is adopted as the electrolyte, decreasing the ohmic polarization of the cell. Porous Ni-YSZ micro-tubular anode substrate with a continuously transitional structure is prepared by the phase-inversion, and no pore former is used in the fabricating process. Ni-ScSZ is introduced between ScSZ electrolyte and Ni-YSZ micro-tubular anode substrate. LSM-ScSZ composite cathode was prepared by the bush-painting method. Single cell is successfully fabricated, exhibiting maximum power densities of 0.38, 0.54, 0.72 and 1.0 W cm ~(- 2) at 650, 700, 750 and 800 C, respectively, with humidified (3%H _2O) hydrogen as fuel and stationary air as oxidant.
机译:电池结构为Ni-YSZ | Ni-ScSZ | ScSZ | LSM-ScSZ | LSM的阳极支撑Sc _2O _3-稳定化ZrO _2(ScSZ)电解质微管固体氧化物燃料电池(MT-SOFC)通过相转化和浸涂技术的组合制备。 ScSZ被用作电解质,降低了电池的欧姆极化。通过相转化制备具有连续过渡结构的多孔Ni-YSZ微管阳极基板,在制造过程中不使用成孔剂。将Ni-ScSZ引入ScSZ电解质和Ni-YSZ微管阳极基板之间。 LSM-ScSZ复合阴极采用灌木涂装法制备。成功制造了单电池,以加湿的(3%H _2O)氢作为燃料并在固定状态下,分别在650、700、750和800 C下表现出最大功率密度分别为0.38、0.54、0.72和1.0 W cm〜(-2)空气作为氧化剂。

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