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An XRD Study of Chemical Self-Discharge in Delithiated Cobalt Oxide

机译:稀氧化钴中化学自放电的XRD研究

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Changes in samples of Li_(1-x)CoO_2 were measured by X-ray diffractometry (XRD) after thermal aging treatments that cause capacity losses in electrochemical cells. Changes in lattice parameters were used to identify lithium re-intercalation into Li_(1-x)CoO_2 when it was aged in the presence of LiClO_4, LiPF_6, and LiAsFg in propylene carbonate (PC). Li~+ re-intercalation could account for the reversible capacity loss. Thermal aging at 75 deg C in pure PC or pure argon gas resulted in other changes that are attributed to the formation of spinel phase. The rate of the lithium re-intercalation increases in the following sequence: LiPF_6 < LiClO_4 < LiAsF_6.
机译:在引起电化学电池容量损失的热老化处理之后,通过X射线衍射法(XRD)测量Li_(1-x)CoO_2样品的变化。晶格参数的变化用于识别锂在Li_(1-x)CoO_2中在碳酸亚丙酯(PC)中存在LiClO_4,LiPF_6和LiAsFg的条件下老化时重新嵌入Li_(1-x)CoO_2中的情况。 Li〜+的重新嵌入可以解决可逆的容量损失。在纯PC或纯氩气中在75摄氏度下的热老化导致其他变化,这归因于尖晶石相的形成。锂重新嵌入的速率按以下顺序增加:LiPF_6

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