Pig Bone Derived Hierarchical Porous Carbon-Supported Platinum Nanoparticles with Superior Electrocatalytic Activity Towards Oxygen Reduction Reaction

摘要

Hierarchical porous carbon (HPC) with nitrogen doped three dimension open macropore structure was prepared from pig bone, and applied for the support material for platinum nanoparticle (Pt NP) electrocatalyst. Compared with carbon black supported Pt NP electrocatalysts, the Pt/HPC exhibited larger electrochemical active surface area and enhanced catalytic properties for the oxygen reduction reaction (ORR) in terms of on-set potential, current density, mass activity and stability. The superior catalytic activity is mainly attributed to the high surface area, hierarchical porous structures and the nitrogen-doped surface properties of the HPC, indicating it is a promising support material for the ORR electrocatalysts.