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Preparation of [C_(60)]Fullerene-CoS2 Nanocomposites and Kinetics Study for Photocatalytic Degradation of Organic Dyes

机译:[C_(60)]富勒烯-CoS2纳米复合材料的制备及光催化降解有机染料的动力学研究

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摘要

Nanosized cobalt disulfide (CoS2) particles were synthesized with 0.08 M cobalt chloride hexahydrate (CoCl2·6H2O) and 0.2 M sodium thiosulfate pentahydrate (Na2S2O3·5H2O) dissolved in distilled water under microwave irradiation. [C_(60)]Fullerene-CoS2 nanocomposites were prepared with nanosized CoS2 particles and [C_(60)]fullerene as heated by 700 °C for 2 h in an electric furnace. X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) identified the heated [C_(60)]fullerene-CoS2 nanocomposites. Heated [C_(60)]fullerene-CoS2 nanocomposites were investigated the activity of photocatalytic degradation as a catalyst in various organic dyes like acid yellow 23, methylene blue, methyl orange, and rhodamine B with ultraviolet light at 254 nm by UV-vis spectrophotometer.
机译:在微波辐射下,将溶解在蒸馏水中的0.08 M氯化钴六水合物(CoCl2·6H2O)和0.2M硫代硫酸钠五水合物(Na2S2O3·5H2O)合成了纳米二硫化钴(CoS2)颗粒。 [C_(60)]富勒烯-CoS2纳米复合材料的制备是在电炉中将纳米尺寸的CoS2颗粒和[C_(60)]富勒烯在700°C下加热2小时。 X射线衍射(XRD),扫描电子显微镜(SEM)和透射电子显微镜(TEM)鉴定了加热的[C_(60)]富勒烯-CoS2纳米复合材料。紫外可见分光光度计研究了加热的[C_(60)]富勒烯-CoS2纳米复合材料在254 nm紫外光下在酸性黄23,亚甲基蓝,甲基橙和若丹明B等多种有机染料中作为催化剂的光催化降解活性。 。

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