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A cellulose acetate based nanocomposite for photocatalytic degradation of methylene blue dye under solar light

机译:醋酸纤维素基纳米复合材料在太阳光下光催化降解亚甲基蓝染料

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摘要

In this work, cellulose acetate-tin (IV) phosphate nanocomposite (CA/TPNC) ion exchanger has been explored for its photocatalytic degradation of methylene blue dye from aqueous solution. The CA/TPNC was characterized using Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM) and X-ray diffraction (XRD). The ion exchange capacity of nanocomposite ion exchanger was observed to be high (1.48 meq g(-1)) for Na+ ion as compared to their inorganic counterpart (0.56 meq g(-1)). The CA/TPNC material was the photocatalytic degradation of methylene blue dye onto CA/TPNC was investigated for 140 min of solar irradiation at 662-nm wavelength. The 80 % the dye was removed onto CA/TPNC after 60 min of irradiation. The rate of photodegradation of MB dye onto CA/TPNC followed the pseudo-first-order kinetic model.
机译:在这项工作中,已经研究了乙酸纤维素-锡(IV)磷酸纤维素纳米复合材料(CA / TPNC)离子交换剂对水溶液中亚甲基蓝染料的光催化降解。使用傅立叶变换红外(FTIR)光谱,透射电子显微镜(TEM)和X射线衍射(XRD)对CA / TPNC进行表征。观察到纳米复合离子交换剂的Na +离子的离子交换容量较高(1.48 meq g(-1)),而无机离子交换剂的离子交换容量为0.56 meq g(-1)。 CA / TPNC材料是在662 nm波长的太阳辐射下140分钟研究了亚甲基蓝染料在CA / TPNC上的光催化降解。照射60分钟后,将80%的染料移至CA / TPNC上。 MB染料在CA / TPNC上的光降解速率遵循伪一级动力学模型。

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