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Studies on biodegradable polymer electrolyte rice starch (RS) complexed with lithium iodide

机译:碘化锂复合可降解高分子电解质大米淀粉的研究

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摘要

Biodegradable and natural rice starch (RS) polymer with lithium iodide salt (LiI) was used to prepare polymer electrolytes using solution cast technique. Polymer electrolyte films were characterized by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), X-ray diffraction (XRD), and scanning electron microscopy (SEM). TGA and DSC thermograms demonstrate that decomposition temperature (T_(dc)) and glass transition temperature (T_g) for rice starch shift upon complexation with lithium iodide salt. Thermolysis studies using TGA show decomposition temperature decreases with the addition of lithium iodide salt. XRD patterns show increase in amorphous behavior with doping of lithium iodide salt. The morphology studies were observed using SEM in terms of smoothness and miscibility.
机译:采用溶液浇铸技术,将可生物降解的天然大米淀粉(RS)聚合物与碘化锂盐(LiI)一起用于制备聚合物电解质。聚合物电解质膜的特征在于热重分析(TGA),差示扫描量热法(DSC),X射线衍射(XRD)和扫描电子显微镜(SEM)。 TGA和DSC热谱图表明,大米淀粉的分解温度(T_(dc))和玻璃化转变温度(T_g)在与碘化锂盐络合后发生移动。使用TGA进行的热解研究表明,添加碘化锂盐会使分解温度降低。 XRD图谱显示出随着碘化锂盐的掺杂非晶态行为的增加。使用SEM在光滑度和可混溶性方面观察了形态学研究。

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