Ceria co-doped with calcium (Ca) and strontium (Sr): a potential candidate as a solid electrolyte for intermediate temperature solid oxide fuel cells

摘要

Co-doped samples of Ce_(0.95-x)Ca_(0.05)Sr_XO+(1.95-x), where (x=0.00, 0.01, 0.02, and 0.03), have been prepared by auto-combustion method and characterized to explore their use as a solid electrolyte for intermediate temperature solid oxide fuel cells (IT-SOFCs). Crystal structure, micro-structure, and ionic conductivity have been characterized by X-ray diffraction, scanning electron microscopy, and impedance spectroscopy, respectively. All the compositions have been found to be single phase. Results show that the samples co-doped with Ca and Sr exhibit higher ionic conductivity than the samples singly doped with Ca in the intermediate temperature range. Ce_(0.93)Ca_90.05)Sr_(0.02)O_(2-δ) exhibits maximum conductivity among all the compositions. This may be a potential candidate as a solid electrolyte for IT-SOFCs.