Electrochemical synthesis and performance of PANI electrode material for electrochemical capacitor

摘要

Polyaniline (PANI) electrode materials doped with sulfuric acid (H2SO4) were prepared by cyclic voltammetry (CV) method in different reaction conditions. The structure and morphology of PANI samples were characterized by Fourier transform infrared spectroscopy and scanning electron microscope. The electrochemical properties of PANI samples were studied by CV, galvanostatic charge/discharge, and electrochemical impedance spectroscopy tests. Additionally, the effects of reaction conditions including aniline concentration, voltammetry scan rate, and deposition time on the morphology and properties of PANI samples were investigated in detail. The results showed that the PANI synthesized under the optimal conditions of 0.2 mol L~(-1) aniline, scan rate 20 mV s~(-1), and deposition time 50 min is in the form of nanorods with a cross-linked network structure. It exhibits an outstanding capacitive performance with good cycle stability and high rate performance. Besides, the specific capacitance of PANI is as high as 757 Fg~(-1).