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The effect of the nature of alkaline metal on the features of the phase formation and structure of complex phosphates M_(3-2x)~IFe_(2-x)Nb_x(PO_4)_3 (x = 0-1.5)

机译:碱性金属性质对络合磷酸盐相形成和结构特征的影响 M_(3-2x)~IFe_(2-x)Nb_x(PO_4)_3 (x = 0-1.5)

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摘要

Double phosphates from the K_2O - P_2O_5 - Fe_2O_3 - Nb_2O_5 system are obtained by high-temperature solid-state reactions. Crystal lattice parameters are calculated from powder diffraction data. Features of the phase formation and the structure of complex orthophosphates M_(3-x)~1Fe_(2-x)Nb_x(PO_4)_3 (M~1 - Li, Na, K; x = 0-1.5) depending of the alkaline metal nature are analyzed.
机译:K_2O-P_2O_5-Fe_2O_3-Nb_2O_5体系中的双磷酸盐是通过高温固相反应获得的。晶格参数是根据粉末衍射数据计算得出的。分析了复合正磷酸盐M_(3-x)~1Fe_(2-x)Nb_x(PO_4)_3 (M~1 - Li, Na, K; x = 0-1.5)的相形成特征和结构。

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