Synthesis and characterization of the dinuclear iron-sulfur cluster {bis[(1,1 '-dithiolatoferrocene-mu-sulfido-ferrate(III)]}(2-)

摘要

The novel iron-sulfur cluster dimer {bis[(1,1'-dithiolatoferrocene-mu-sulfido-ferrate(III)]}(2-) is Prepared as the tetrapropylammonium salt in a one-pot synthesis from 1,1'-trithiaferrocenophane, FeCl3, and (BuS-)-Bu-t. The X-ray crystallography, electronic spectroscopy, electrochemistry, and magnetic susceptibility of this complex are reported and compared and contrasted to previously prepared iron-sulfur dimer complexes with organic thiolate ligands. (C) 2000 Elsevier Science S.A. All rights reserved. [References: 20]