SYNTHESIS AND CRYSTAL STRUCTURE OF MU-4-OXO-HEXA-(MU(2)-(N,S)-1-METHYLIMIDAZOLINE-2-THIONATO)-TETRAZINC(II)

摘要

Electrochemical oxidation of zinc in a solution of 1-methylimidazoline-2-thione (MeImtH) in acetonitrile, gives [Zn4O(MeImt)(6)] whose crystal structure has been determined by X-ray diffraction. This compound contains a central oxygen atom tetrahedrally bonded to four zinc atoms, bridged by six 1-methylimidazoline-2-thionato ligands along the edges of the tetrahedron. Each zinc atom exhibits tetrahedral coordination. [References: 33]