Novel metal-organic 1-D oordination polymer based on pyrazine-2,5- dicarboxylate ligands: Synthesis and structure investigation

Isaeva V.; Chernyshev V.; Afonina E.; Tkachenko O.; Klementiev K.; Nissenbaum V.; Grünert W.; Kustov L.

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Novel metal-organic 1-D oordination polymer based on pyrazine-2,5- dicarboxylate ligands: Synthesis and structure investigation

机译：基于吡嗪-2,5-二羧酸酯配体的新型金属有机一维配位聚合物：合成与结构研究

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The novel Zn(II) based complex, [Zn(pz25dc)(DMF)_2] (1) (where pz25dc stands for pyrazine-2,5-dicarboxylate ligands) has been synthesized by the direct mixing method. This structure confirmed by a combination of physic-chemical methods features a 1-D linear polymeric chain. The local structure of a Zn atom in the unit cell of [Zn(pz25dc)(DMF)_2] derived from EXAFS data is in a good agreement with that revealed from PXRD data.

机译：通过直接混合方法合成了新颖的基于Zn（II）的络合物[Zn（pz25dc）（DMF）_2]（1）（其中pz25dc代表吡嗪-2,5-二羧酸酯配体）。通过物理化学方法相结合证实的这种结构具有1-D线性聚合物链。由EXAFS数据得出的[Zn（pz25dc）（DMF）_2]晶胞中Zn原子的局部结构与从PXRD数据揭示的局部结构非常吻合。

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来源
《Inorganica Chimica Acta》 |2011年第1期|共6页
作者
Isaeva V.; Chernyshev V.; Afonina E.; Tkachenko O.; Klementiev K.; Nissenbaum V.; Grünert W.; Kustov L.;
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正文语种 eng
中图分类无机化学;
关键词
Metal organic coordination polymers; Metal organic frameworks; Network; Structural motif;

机译：金属有机配位聚合物;金属有机骨架;网络;结构基序;

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1. Novel metal-organic 1-D oordination polymer based on pyrazine-2,5- dicarboxylate ligands: Synthesis and structure investigation [J] . Isaeva V., Chernyshev V., Afonina E., Inorganica Chimica Acta . 2011,第1期

机译：基于吡嗪-2,5-二羧酸酯配体的新型金属有机一维配位聚合物：合成与结构研究
2. Synthesis, structure and characterization of two new metal-organic coordination polymers based on the ligand 5-iodobenzene-1,3-dicarboxylate [J] . Zhang Xu, Zhang Lei, Wang Meng-Jie, Acta crystallographica. Section F, Structural biology communications . 2015,第9期

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Novel metal-organic 1-D oordination polymer based on pyrazine-2,5- dicarboxylate ligands: Synthesis and structure investigation

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