The [Re(N)((PN)-N-boolean AND)] building-block

摘要

The formation of the uncommon molecular ion fragment [Re(N)((PN)-N-boolean AND)] is ESI-MS conditions is confirmed by the synthesis and characterization of the representative [Re(N)Cl-2((PNMe2)-N-boolean AND)PPh3] complex. This species contains the unprecedented [Re(N)((PNMe2)-N-boolean AND)] moiety which constitutes an additional example of metal-based building-block potentially useful in the design of rhenium radiopharmaceuticals.