Oxoselenide triangular molybdenum clusters: Synthesis and characterization of [Mo_3SeO_3(acac)_3(py)_3]PF _6

Abramov P.A.; Sokolov M.N.; Peresypkina E.V.; Mirzaeva I.V.; Moroz N.K.; Vicent C.; Hernandez-Molina R.; Goya M.C.; Arévalo M.C.; Fedin V.P.

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Oxoselenide triangular molybdenum clusters: Synthesis and characterization of [Mo_3SeO_3(acac)_3(py)_3]PF _6

机译：氧代硒化物三角钼簇：[Mo_3SeO_3（acac）_3（py）_3] PF _6的合成与表征

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New cluster complex [Mo_3SeO_3(acac) _3(py)_3]~+ was obtained by ligand substitution in the aqua complex [Mo_3SeO_3(H_2O) _9]~(4+). Crystal structure was determined for [Mo _3SeO_3(acac)_3(py)_3]PF _6·C_6H_5CH_3. The complex was characterized by ~(77)Se NMR, electrospray mass-spectrometry, and cyclic voltammetry. DFT calculations were used to confirm the assignment of chemical shift and to study Mo-Mo bonding in the cluster core.

机译：通过在水络合物[Mo_3SeO_3（H_2O）_9]〜（4+）中进行配体置换得到新的簇络合物[Mo_3SeO_3（acac）_3（py）_3] +。测定[Mo _3SeO_3（acac）_3（py）_3] PF _6·C_6H_5CH_3的晶体结构。通过〜（77）Se NMR，电喷雾质谱和循环伏安法对络合物进行表征。 DFT计算用于确认化学位移的分配并研究簇核中的Mo-Mo键。

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《Inorganica Chimica Acta》 |2011年第1期|共6页
作者
Abramov P.A.; Sokolov M.N.; Peresypkina E.V.; Mirzaeva I.V.; Moroz N.K.; Vicent C.; Hernandez-Molina R.; Goya M.C.; Arévalo M.C.; Fedin V.P.;
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正文语种 eng
中图分类无机化学;
关键词
~(77)Se NMR; Electronic structure; Molybdenum clusters; NMR shift calculations; Oxide clusters; Selenide clusters;

机译：〜（77）Se NMR;电子结构;钼簇;NMR位移计算;氧化物簇;硒簇;

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1. Oxoselenide triangular molybdenum clusters: Synthesis and characterization of [Mo_3SeO_3(acac)_3(py)_3]PF _6 [J] . Abramov P.A., Sokolov M.N., Peresypkina E.V., Inorganica Chimica Acta . 2011,第1期

机译：氧代硒化物三角钼簇：[Mo_3SeO_3（acac）_3（py）_3] PF _6的合成与表征
2. Synthesis, Structural Characterization and Reactivity of Two New Triangular Molybdenum Cluster Compounds: Mo_3Te_7-[S_2CN(CH_2CH_2OH_2]_3I and Mo_3Te_4Y_3[S_2P(~iPrO)_2]_3I (Y_3 = 1.43Te + 1.57S) [J] . YANG Wen-Bin, LIN Xiang, LU Can-Zhong, Chinese Journal of Chemistry . 2002,第4期

机译：两种新型三角形钼簇化合物Mo_3Te_7- [S_2CN（CH_2CH_2OH_2] _3I和Mo_3Te_4Y_3 [S_2P（〜iPrO）_2] _3I（Y_3 = 1.43Te + 1.57S）的合成，结构表征和反应性
3. Synthesis, Structural Characterization and Reactivity of Two New Triangular Molybdenum Cluster Compounds: Mo3Te7 S2CN( CH2CH2OH)23I and Mo3Te4Y3S2P(iPrO)23I (Y3 =1.43Te + 1.57S) [J] . YANGWen-Bin(杨文斌), LINXiang(林祥), LUCan-Zhong(卢灿忠), 中国化学（英文版） . 2002,第004期

机译：两种新型三角形钼簇化合物Mo3Te7 S2CN（CH2CH2OH）2 3I和Mo3Te4Y3 S2P（iPrO）2 3I（Y3 = 1.43Te + 1.57S）的合成，结构表征和反应性
4. Synthesis and Characterization of CuO2(acac)2 Supported on Functionalized MCM41 Containing Thiourea Ligand [C] . Ahmad A., Rasid H.M., Fadzil A.H., 2011 2nd International Conference on Chemistry and Chemical Engineering . 2011

机译：含硫脲配体的功能化MCM41负载CuO2（acac）2的合成与表征
5. Syntheses and characterizations of monomeric molybdenum(VI) complexes with bidentate phosphine oxide ligands and dimeric and tetrameric molybdenum(V) clusters with benzoic acid and phosphinic acid derivatives, containing molybdenum oxide, molybdenum(2) dioxide (mu-oxygen) and molybdenum(4) tetroxide (mu3-oxygen) structural motifs [D] . Sreehari, Soumyashree 2010

机译：具有二齿膦氧化物配体的单体钼（VI）配合物以及具有苯甲酸和次膦酸衍生物的二聚和四聚钼（V）簇的合成和表征，其中包含氧化钼，二氧化钼（mu-oxygen）和钼（4））四氧化物（mu3-氧）结构基序
6. Synthesis and Characterization of the Complexes of Pentane-24-dione with Nickel(II) and Cobalt(III): Ni(acac)2·0.5CH3OH and Co(acac)2NO3·2H2O (acac = Pentane-24-dione) [O] . Yang Qu, Hai-Liang Zhu, Zhong-Lu You, 2004

机译：戊烷-24-二酮与镍（II）和钴（III）：Ni（acac）2·0.5CH3OH和Co（acac）2NO3·2H2O（acac = Pentane- 24-二酮）
7. Studies of molybdenum-molybdenum bonded species: 1. Synthesis and characterization of a reduction product of Cs3Mo2Cl8H; 2. Mixed sulfur chlorine substituted hexanuclear molybdenum clusters [O] . Luly, Matthew Hermes 1982

机译：钼-钼键合物种的研究：1. Cs3Mo2Cl8H还原产物的合成与表征； 2.混合硫氯取代的六核钼簇
8. Studies of Molybdenum-Molybdenum Bonded Species. 1. Synthesis and Characterization of a Reduction Product of Cs sub 3 Mo sub 2 Cl sub 8 H. 2. Mixed Sulfur/Chlorine-Substituted Hexanuclear Molybdenum Clusters [R] . Luly, M. H. 1982

机译：钼钼键合物的研究。 1.Cs sub 3 mo sub 2 Cl sub 8 H的还原产物的合成和表征.2。混合的硫/氯取代的六核钼簇

Oxoselenide triangular molybdenum clusters: Synthesis and characterization of [Mo_3SeO_3(acac)_3(py)_3]PF _6

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