Synthesis, structures, and luminescence properties of mixed ligand Cd(II) and Zn(II) coordination compounds mediated by 1,2-bis(4-pyridyl)ethane

摘要

Interaction of cadmium(II) or zinc(II) acetate with 1,2-bis(4-pyridyl) ethane (bpe) in the presence of dioxime(1,2-cyclohexanedionedioxime = NioxH _2 or diphenylglyoxime = dpgH_2) resulted in three complexes with the compositions [Cd_2(CH_3COO)_4(NioxH _2)_2(bpe)(H_2O)_2] (1), [Cd(CH _3COO)_2(bpe)(H_2O)]n (2) and [Zn(CH_3COO)_2(NioxH_2)(bpe)(H_2O)] _n (3), which were characterized by single-crystal X-ray diffraction, elemental analysis, IR, and luminescence spectroscopy. Dioxime-containing binuclear molecule 1 and 1D linear polymer 3 possess moderate luminescence properties, while the dioxime-free 1D polymer 2 demonstrates strong blue luminescence.