首页> 外文期刊>Inorganica Chimica Acta >The complexes: RhCl(P-N)(THP), where P-N is P,N-chelated o-diphenylphosphino-N,N-dimethylaniline and THP is tris(hydroxymethyl)phosphine, and RhCl[(O)P-N][THP(O)] containing O-bonded phosphine oxides
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The complexes: RhCl(P-N)(THP), where P-N is P,N-chelated o-diphenylphosphino-N,N-dimethylaniline and THP is tris(hydroxymethyl)phosphine, and RhCl[(O)P-N][THP(O)] containing O-bonded phosphine oxides

机译:配合物:RhCl(PN)(THP),其中PN是P,N-螯合的邻二苯膦基-N,N-二甲基苯胺,THP是三(羟甲基)膦,以及RhCl [(O)PN] [THP(O)含O键的氧化膦

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摘要

The complex RhCl(P-N)(THP) (1) is synthesized under argon from RhCl(cod)(THP) and P-N, and is structurally characterized; P-N = P, N-chelated o-diphenylphosphino-N,N-dimethylaniline, THP = tris(hydroxymethyl) phosphine, and cod = 1,5-cyclo-octadiene. The corresponding synthesis in air yields RhCl[(O)P-N][THP(O)] (2), containing O-bonded phosphine oxide ligands. (C) 2007 Elsevier B.V. All rights reserved.
机译:配合物RhCl(P-N)(THP)(1)在氩气下由RhCl(cod)(THP)和P-N合成,并进行结构表征; P-N = P,N-螯合的邻二苯基膦基-N,N-二甲基苯胺,THP =三(羟甲基)膦,cod = 1,5-环辛二烯。在空气中的相应合成会生成RhCl [(O)P-N] [THP(O)](2),其中含有O键合的氧化膦配体。 (C)2007 Elsevier B.V.保留所有权利。

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