Synthesis, characterisation and crystal structures of a few coordination complexes of nickel(II), cobalt(III) and zinc(II) with N '-[(2-pyridyl)methylene]salicyloylhydrazone Schiff base

摘要

Four new coordination complexes, Ni-II(L)(2) (1), [Co-III (L)(2)]ClO4 (2), [Zn(HL)(L)]ClO4 center dot H2O (3) and [Zn(L)(2)][Zn(L)(HL)]ClO4 center dot 7H(2)O (4) (where L is a monoanion of a Schiff base ligand, N'-[(2-pyridyl)methylene]salicyloylhydrazone (HL) with NNO tridentate donor set), have been synthesised and systematically characterised by elemental analysis, spectroscopic studies and room temperature magnetic susceptibility measurements. Single crystal X-ray diffraction analysis reveals that 1 is a neutral complex, while 2-4 are cationic complexes. Among them, 4 is a rare type of cationic complex with two molecules in the asymmetric unit. The ligand chelates the metal centre with two nitrogen atoms from the pyridine and imino moieties and one oxygen atom coming from its enolic counterpart. All the reported complexes show distorted octahedral geometry around the metal centres, with the two metal-N (imino) bonds being significantly shorter than the two metal-N (Py) bonds. (c) 2007 Elsevier B.V. All rights reserved.