Fabrication of two- and three-dimensional model catalyst systems with monodispersed platinum nanoparticles as active metal building blocks

摘要

Well-defined Pt monodispersed nanoparticles within the catalytically relevant 1-10 nm size regime were synthesized in solution phase by several synthetic methods which differed in the choice of reducing agent, surface stabilizer, reaction temperature and solvent. Three-dimensional model catalysts were fabricated by incorporating the metal nanoparticles into ordered channels of high surface area mesoporous oxides such as SiO2, Al2O3 and Ta2O5 through either sonication or direct synthesis of the oxide support around the particles. Deposition of the same nanocrystals onto silica supports by means of the Langmuir-Schaeffer technique produced two-dimensional model catalysts. (c) 2005 Elsevier B.V. All rights reserved.