Group 10 derivatives of the silylated sterically hindered aromatic thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2]. The crystal structures of trans-[Pd(PPh3)(2)(SC6H4-2-SiPh3)(2)], z-[Pt(PPh3)(2)(Cl)(Sc6H4-2-SiPh3)], e-[Pt(PPh3)(2)(Cl)-(SC6H4-2-Si

摘要

The reactivity of the silylated sterically hindered thiolates [C6H4SH-2-SiPh3] and [C6H4SH-2-SiCH3Ph2] has been examined with transition metal complexes of group 10. A series of palladium(II) and platinum(II) complexes were obtained. Analysis of these complexes by different spectroscopic techniques and single crystal X-ray diffraction studies revealed the formulations to be dependent of the stoichiometry and relative size of the metal center and thiolate. Analogous reactions with nickel complexes afforded oxidation decomposition products. (c) 2006 Elsevier B.V. All rights reserved.