Syntheses and first structural analyses of Cu(I)-PS complexes with bidentate 1,1-diphenyl-1-phospha-4-thiapentane (mtdpp) and quadridentate 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (2,3,2-SPPS): successful synthetic route for monomeric [Cu(mtd

摘要

Mononuclear and binuclear complexes of Cu(I) with bidentate and quadridentate phosphine-thioether hybrid ligands were successfully isolated for the first time by mixing aqueous copper(II) with each corresponding ligand: the structures of these complexes were analyzed by the X-ray crystallographic method and the synthetic route for these complexes was clarified on the basis of the electrochemical behaviors of these complexes in solution. (C) 2003 Elsevier B.V. All rights reserved. [References: 23]