Synthesis and structures of 2.nmetacyclophane-1,2-diones

Tatsunori Saisyo; Mikiko Shiino; Tomoe ShimizuArjun PaudelTakehiko Yamato

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Synthesis and structures of 2.nmetacyclophane-1,2-diones

机译：2.n间环烷-1,2-二酮的合成和结构

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摘要

McMurry cyclisation of 1,n-bis(5-formyl-2-methoxyphenyl)alkanes afforded dimethoxy2.nmetacyclophan-1-enes and dimethoxy2.nmetacyclophane-1,2-diols, in which latter one was converted to dimethoxy2.nmetacyclophane-1,2-diones by Albright–Goldman oxidation.

机译：1，n-双（5-甲酰基-2-甲氧基苯基）烷烃的麦克默里环化得到二甲氧基[2.n]间环烷-1-烯和二甲氧基[2.n]间环烷-1,2-二醇，其中后者通过奥尔布赖特-戈德曼氧化转化为二甲氧基[2.n]间环烷-1,2-二酮。

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来源
《Journal of chemical research: reviews and research papers from all branches of chemistry》 |2008年第8期|479-483|共5页
作者
Tatsunori Saisyo; Mikiko Shiino; Tomoe ShimizuArjun PaudelTakehiko Yamato;
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作者单位

Department of Applied Chemistry, Faculty of Science and Engineering, Saga University, Honjo-machi 1, Saga 840-8502, Japan;

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原文格式 PDF
正文语种英语
中图分类化学;
关键词
cyclophanes; McMurry reaction; 2.nmetacyclophane-1; 2-diol; conformation; oxidation; 1; 2-diketones;

机译：环烷;麦克默里反应;[2.n]间环烷-1;2-二醇;构象;氧化;1;2-二酮;

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Synthesis and structures of 2.nmetacyclophane-1,2-diones

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