Abnormal broadening of free radical EPR lines: A new test probe for singlet dioxygen in solution

Gekhman AE.; Minin VV.; Larin GM.; Moiseev II.; Moisseva NI.

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Abnormal broadening of free radical EPR lines: A new test probe for singlet dioxygen in solution

机译：自由基EPR线的异常扩宽：溶液中单重态双氧的新测试探针

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ESR signals of V(V)/superoxide radical anion complex and a number of stable nitroxyl radicals were found to undergo abnormal (up to 10 G) broadening in the presence of singlet dioxygen in aqueous and AcOH solutions. [References: 22]

机译：发现在水溶液和AcOH溶液中存在单重态双氧的情况下，V（V）/超氧化物自由基阴离子络合物的ESR信号和许多稳定的硝酰基自由基经历异常（最多10 G）加宽。 [参考：22]

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |1999年第15期|共2页
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Gekhman AE.; Minin VV.; Larin GM.; Moiseev II.; Moisseva NI.;
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正文语种 eng
中图分类化学;
关键词
Hydrogen-peroxide; Vanadium v; Oxygen; Oxidation; Complex; Disproportionation; System;

机译：过氧化氢;钒v;氧;氧化;络合物;歧化;体系;

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1. Abnormal broadening of free radical EPR lines: A new test probe for singlet dioxygen in solution [J] . Gekhman AE., Minin VV., Larin GM., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1999,第15期

机译：自由基EPR线的异常扩宽：溶液中单重态双氧的新测试探针
2. EPR AND SPECTROPHOTOMETRIC STUDIES OF FREE RADICALS (O-2-CENTER-DOT(-), CENTER-DOT-OH, BPD-MA-CENTER-DOT(-)) AND SINGLET OXYGEN (O-1(2)) GENERATED BY IRRADIATION OF BENZOPORPHYRIN DERIVATIVE MONOACID RING A [J] . Hadjur C., Monnier P., Vandenbergh H., Photochemistry and Photobiology: An International Journal . 1997,第5期

机译：EPR和分光光度法研究辐照产生的自由基（O-2-CENTER-DOT（-），CENTER-DOT-OH，BPD-MA-CENTER-DOT（-））和单氧（O-1（2））卟啉衍生物单环酸A的合成
3. EPR Line Shifts and Line Shape Changes due to Spin Exchange of Nitroxide Free Radicals in Liquids: 6. Separating Line Broadening due to Spin Exchange and Dipolar Interactions [J] . Barney L. Bales, Michelle Meyer, Steve Smith, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2009,第17期

机译：由于液体中一氧化氮自由基的自旋交换而引起的EPR线位移和线形变化：6.由于自旋交换和偶极相互作用而使线变宽
4. Free-radical Probes for Functional in vivo EPR Imaging [C] . S. Subramanian, M. C. Krishna Genetically Engineered and Optical Probes for Biomedical Applications IV; Progress in Biomedical Optics and Imaging; vol.8 no.26; Proceedings of SPIE-The International Society for Optical Engineering; vol.6449 . 2007

机译：用于体内EPR成像的自由基探针
5. Free radical metabolite of munition RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) and 1-nitroso degradation product MNX determined with electron paramagnetic resonance (EPR) and study the toxic effects of deepwater horizon crude oil in rats. [D] . Al Suliman, Rami Jaffar. 2016

机译：用电子顺磁共振（EPR）测定的RDX武器的自由基代谢产物（六氢-1,3,5-三硝基-1,3,5-三嗪）和1-亚硝基降解产物MNX并研究深水地平线原油的毒性在大鼠中。
6. EPR Line Shifts and Line Shape Changes Due to Spin Exchange of Nitroxide Free Radicals in Liquids 6. Separating Line Broadening due to Spin Exchange and Dipolar Interactions [O] . Barney L Bales, Michelle Meyer, Steve Smith, -1

机译：EpR线路班次和线路形状的变化由于自旋氮氧自由由于自旋交换和偶极相互作用自由基液体中分离6线扩张的交易所
7. EPR Line Shifts and Line Shape Changes Due to Spin Exchange of Nitroxide-Free Radicals in Liquids 4. Test of a Method to Measure Re-Encounter Rates in Liquids Employing 15N and 14N Nitroxide Spin Probes [O] . Barney L. Bales, Miroslav Peric 2016

机译：由于液体中无氮自由基的自旋交换引起的EpR线移位和线形变化4.使用15N和14N氮氧自旋探针测量液体中再遇率的方法测试

Abnormal broadening of free radical EPR lines: A new test probe for singlet dioxygen in solution

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