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首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Electrochemical reduction of nitrogenous ligands at a conserved dinuclear metal-sulfur site: Cleavage of the N=N bond of phenyldiazene and reduction of an imide to NH3

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Electrochemical reduction of nitrogenous ligands at a conserved dinuclear metal-sulfur site: Cleavage of the N=N bond of phenyldiazene and reduction of an imide to NH3

机译：保守的双核金属-硫位处的氮配体的电化学还原：裂解苯基二氮烯的N = N键并将酰亚胺还原为NH3

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |1999年第9期|共2页
作者
Petillon FY.; Talarmin J.; Muir KW.; Schollhammer P.;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
N-n bond; Catalytic reduction; Dinitrogen cleavage; Possible relevance; Complexes; Hydrazine; Protonation; Chemistry; Oxidation; Ammonia;

机译：N-n键;催化还原;二氮裂解;可能的相关性;络合物;肼;质子化;化学;氧化;氨;

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1. Electrochemical reduction of nitrogenous ligands at a conserved dinuclear metal-sulfur site: Cleavage of the N=N bond of phenyldiazene and reduction of an imide to NH3 [J] . Petillon FY., Talarmin J., Muir KW., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1999,第9期

机译：保守的双核金属-硫位处的氮配体的电化学还原：裂解苯基二氮烯的N = N键并将酰亚胺还原为NH3
2. Metal vs Ligand Reduction in Complexes of Dipyrido[3,2-a:2',3'-c]phenazine and Related Ligands with [(C_5Me_5)CIM]~+ (M = Rh or Ir): Evidence for Potential Rather Than Orbital Control in the Reductive Cleavage of the Metal-Chloride Bond [J] . Sascha Berger, Jan Fiedler, Ralf Reinhardt, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2004,第4期

机译：双吡啶并[3,2-a：2'，3'-c]吩嗪和相关配体与[（C_5Me_5）CIM]〜+（M = Rh或Ir）的配合物中金属与配体的还原：可能比轨道的证据金属-氯键还原裂解的控制
3. Cyclopalladated complexes containing 2-C6R4PPh2 ligands (R = H, F): one-electron electrochemical reduction leading to metal-carbon sigma-bond cleavage via palladium(I) [J] . Kar Gopa, Priver Steven H., Jones Lathe A., Dalton transactions: An international journal of inorganic chemistry . 2015,第7期

机译：含2-C6R4PPh2配体的环钯配合物（R = H，F）：单电子电化学还原导致金属-碳σ键通过钯（I）裂解
4. Electrochemical Reduction of Carbon Dioxide Catalyzed by Cofacial Dinuclear Metalloporphyrin [C] . Osamu Enoki, Takane Imaoka, Kimihisa Yamamoto, IUPAC international symposium on macromolecule-metal complexes . 2003

机译：COFacial DITUCOLOPOLORIN催化的二氧化碳电化学还原
5. Single-site molybdenum(IV) mediated bond cleavage reactions and ligand parameterization using a chromium(VI) nitrido platform. [D] . DiFranco, Stephen Andrew. 2013

机译：单中心钼（IV）介导的键裂解反应和使用铬（VI）氮离子平台的配体参数化。
6. Reductive cleavage of NN′-di-tert-butylcarbodiimide generates tert-butylcyanamide ligands (Me3CNCN)− that bind potassium both end-on and side-on in the same single crystal [O] . Amanda B. Chung, Joseph W. Ziller, William J. Evans 2020

机译：NN-二叔丁基碳二亚胺的还原裂解生成叔丁基氰胺配体（Me3CNCN）-在同一单晶中端部和侧面结合钾
7. Dinuclear Rhenium Complex with a Proton Responsive Ligand as a Redox Catalyst for the Electrochemical CO2 Reduction [O] . Alexander Wilting, Thorsten Stolper, Ricardo A. Mata, 2017

机译：用金属铼络合物与质子响应配体作为电化学二氧化碳的氧化还原催化剂
8. Redox Catalysis Involving Substrate Photooxidation with Catalyst Regeneration bySubstrate Reduction. Simultaneous Oxidative C-H Bond Cleavage and Reductive C-S Bond Cleavage in Thioethers Catalyzed by W10O324- [R] . Chambers, R. C., Hill, C. L. 1990

机译：氧化还原催化与底物光氧化反应的催化剂再生通过底物还原。 W10O324催化的硫醚同时氧化C-H键断裂和还原C-s键断裂

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