Preparation and X-ray Strutures of Alkali-Metal Derivatives of the Ambidentate Anions [~tBuN(E)P(#mu#-N~TBu)_2P(EN~tBu]~(2-) (E = S, Se) adn [~tBuN(Se)P(#mu#-N~tBu)_2PN(H)_~tBu)]~-

Tristram Chivers; Mark Krahn; Masood Parvez; Gabriele Schatte

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Preparation and X-ray Strutures of Alkali-Metal Derivatives of the Ambidentate Anions [~tBuN(E)P(#mu#-N~TBu)_2P(EN~tBu]~(2-) (E = S, Se) adn [~tBuN(Se)P(#mu#-N~tBu)_2PN(H)_~tBu)]~-

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Preparation and X-ray Strutures of Alkali-Metal Derivatives of the Ambidentate Anions [~tBuN(E)P(#mu#-N~TBu)_2P(EN~tBu]~(2-) (E = S, Se) adn [~tBuN(Se)P(#mu#-N~tBu)_2PN(H)_~tBu)]~-

机译：[〜tBuN（E）P（＃mu＃-N〜TBu）_2P（EN〜tBu]〜（2-）（E = S，Se）adn的碱金属衍生物的制备和X射线结构[〜tBuN（Se）P（＃mu＃-N〜tBu）_2PN（H）_〜tBu）]-

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The arnbidentate dianions [IBuN(E)P(#mu#-N'BU)_2P(E)NIBu]~(2-) (Sa, E = S; Sb, E = Se) are obtained as their disodiurn and dipotassium salts by the reaction of cis-rBu(H)N(E)P(u-NIBu)_2P(E)N(H)tBu] (6&, E = S; 6b, E = Se), with 2 equiv of MN(SiMe_3)_2 (M = Na, K) in THF at 23 °C. The corresponding dilithium derivative is prepared by reacting 6& with 2 equiv of IBuLl in THF at reflux. The X-ray structures of five complexes of the type [(THF),Mh- rBuN(E)P(u-NBu)_2P(E)NBu] (9, M = Li, E = S, x = 2; lla/llb, M = Na, E = S/

机译：获得双歧双阴离子[IBuN（E）P（＃mu＃-N'BU）_2P（E）NIBu]〜（2-）（Sa，E = S; Sb，E = Se）通过顺式-rBu（H）N（E）P（u-NIBu）_2P（E）N（H）tBu]（6＆，E = S; 6b，E = Se）与2当量的MN（在23°C下于THF中的SiMe_3）_2（M = Na，K）。通过使6＆与2当量的IBul1在THF中回流反应来制备相应的二锂衍生物。 [[THF），Mh-rBuN（E）P（u-NBu）_2P（E）NBu]类型的五种配合物的X射线结构（9，M = Li，E = S，x = 2; lla / llb，M = Na，E = S /

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2001年第11期|共7页
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Tristram Chivers; Mark Krahn; Masood Parvez; Gabriele Schatte;
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1. Preparation and X-ray Strutures of Alkali-Metal Derivatives of the Ambidentate Anions [~tBuN(E)P(#mu#-N~TBu)_2P(EN~tBu]~(2-) (E = S, Se) adn [~tBuN(Se)P(#mu#-N~tBu)_2PN(H)_~tBu)]~- [J] . Tristram Chivers, Mark Krahn, Masood Parvez, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第11期

机译：[〜tBuN（E）P（＃mu＃-N〜TBu）_2P（EN〜tBu]〜（2-）（E = S，Se）adn的碱金属衍生物的制备和X射线结构[〜tBuN（Se）P（＃mu＃-N〜tBu）_2PN（H）_〜tBu）]-
2. Preparation and X-ray strcutues of Cu(I),Ni(II),and Pd(II)(N,S)complexes of the monoainon[(~tBuN)(S)P(#mu#-N~tBu)]~- and a Pt(II) (S,S')complex of the dianion [(~tBuN)(S)P(#mu#-N~tBu)_2P(S)(N~tbU)]~(2-) [J] . Tristram Chivers, Chantall Fedorchuk, Mark Krahn, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第8期

机译：单胺[（〜tBuN）（S）P（＃mu＃-N〜tBu）]的Cu（I），Ni（II）和Pd（II）（N，S）配合物的制备和X射线谱〜-和二价阴离子[（〜tBuN）（S）P（＃mu＃-N〜tBu）_2P（S）（N〜tbU）]〜（2-的Pt（II）（S，S'）络合物）
3. Preparation and X-ray strcutues of Cu(I),Ni(II),and Pd(II)(N,S)complexes of the monoainon[(~tBuN)(S)P(#mu#-N~tBu)]~- and a Pt(II) (S,S')complex of the dianion [(~tBuN)(S)P(#mu#-N~tBu)_2P(S)(N~tbU)]~(2-) [J] . Tristram Chivers, Chantall Fedorchuk, Mark Krahn, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第8期

机译：单胺[（〜tBuN）（S）P（＃mu＃-N〜tBu）]的Cu（I），Ni（II）和Pd（II）（N，S）配合物的制备和X射线谱〜-和二价阴离子[（〜tBuN）（S）P（＃mu＃-N〜tBu）_2P（S）（N〜tbU）]〜（2-的Pt（II）（S，S'）络合物）
4. Solid phase synthesis of seleno-methionine peptides by tBoc/Bzl and Fmoc/tBu protection strategy suitable for the crystallographic phase determination by multi-wavelength anomalous diffraction (MAD) [C] . Stafan R.K.Hoffmann, Christine A.Deillon, Bernd Gutte the International Peptide Symposium . 2001

机译：通过多波长异常衍射（MAD）的TBOC / BZL和FMOC / TBU保护策略通过TBOC / BZL和FMOC / TBU保护策略合成Seleno-甲硫氨酸肽的固相合成。通过多波长异常衍射（MAD）
5. Structurally Defined Potassium-Mediated Zincation of Pyridine and 4-R-Substituted Pyridines (R=Et iPr tBu Ph and Me2N) by Using Dialkyl–TMP–Zincate Bases [O] . William Clegg, Ben Conway, David V Graham, -1

机译：通过使用二烷基-TMP-锌盐碱基的结构定义为钾介导的吡啶和4-R取代的吡啶锌（R = EtiPrtBuPh和Me2N）
6. Synthese der Si-funktionellen Acetylsilane tBu(Me(_3)SiCH(_2))MeC(O)SiF und tBu(Me(_3)SiCH(_2))MeC(O)SiH sowie Synthese und Kristallstruktur des Acetylsilanols tBu(Me(_3)SiCH(_2))MeC(O)SiOH: Substrate für mikrobielle Reduktionen [O] . Tacke Reinhold, Hengelsberg H., Klingner E., 2012

机译：Si-官能乙酰基硅烷tBu（Me （_ 3 ）SiCH （_ 2 ））MeC（O） SiF和tBu（Me （_ 3 ）SiCH （_ 2 ））MeC（O）的合成SiH和乙酰硅烷醇tBu（Me （_ 3 ）SiCH （_ 2 ））MeC（O） SiOH的合成和晶体结构：微生物还原的底物

Preparation and X-ray Strutures of Alkali-Metal Derivatives of the Ambidentate Anions [~tBuN(E)P(#mu#-N~TBu)_2P(EN~tBu]~(2-) (E = S, Se) adn [~tBuN(Se)P(#mu#-N~tBu)_2PN(H)_~tBu)]~-

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