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首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Zinc Diphosphonates Templated by Organic Amines: Syntheses and Characterizations of [NH_3(CH_2)_2NH]Zn(hedpH_2)_2·2H_2O and [NH_3(CH_2)_nNH_3]Zn_2(hedpH)_2·2H_2O 9n = 4,5,6) (hedp = 1-Hydroxyethylidenediphosphonate)
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Zinc Diphosphonates Templated by Organic Amines: Syntheses and Characterizations of [NH_3(CH_2)_2NH]Zn(hedpH_2)_2·2H_2O and [NH_3(CH_2)_nNH_3]Zn_2(hedpH)_2·2H_2O 9n = 4,5,6) (hedp = 1-Hydroxyethylidenediphosphonate)

机译:有机胺为模板的二膦酸锌锌:[NH_3(CH_2)_2NH] Zn(hedpH_2)_2·2H_2O和[NH_3(CH_2)_nNH_3] Zn_2(hedpH)_2·2H_2O的合成与表征9n = 4,5,6)(hedp = 1-羟基乙二烯二膦酸酯)

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摘要

Four new zinc diphosphonate compounds with formuloas [NH_3(CH_2)_2NH_3]Zn(hedpH_2)_2·2H_2O, 1, [NH_3(CH_2)_nNH_3]Zn_2(hedpH)_2·2H_2O, (n = 4,2; n = 5,3; n = 6,4') (hedp = 1-hydroxyethylidenediphosphate) have been synthesized under hydrothermal conditions at 110 deg C and in the rpesence of alkylenediamines NH_2(CH_2)_nNH_2 (n = 2,4,5,6).
机译:四种新的具有式[NH_3(CH_2)_2NH_3] Zn(hedpH_2)_2·2H_2O,1,[NH_3(CH_2)_nNH_3] Zn_2(hedpH)_2·2H_2O的二膦酸锌化合物(n = 4,2; n = 5, 3; n = 6,4′)(hedp = 1-羟乙基二烯二磷酸)已经在水热条件下在110℃和亚烷基二胺NH 2(CH 2)_nNH 2存在下合成(n = 2,4,5,6)。

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