Model for the cofactor formation reaction of E-coli ribonucleotide reductase. From a diiron(II) precursor to an (FeFeIV)-Fe-III species via a peroxo intermediate

MacMurdo VL.; Que L.; Zheng H.

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Model for the cofactor formation reaction of E-coli ribonucleotide reductase. From a diiron(II) precursor to an (FeFeIV)-Fe-III species via a peroxo intermediate

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Model for the cofactor formation reaction of E-coli ribonucleotide reductase. From a diiron(II) precursor to an (FeFeIV)-Fe-III species via a peroxo intermediate

机译：大肠杆菌核糖核苷酸还原酶辅因子形成反应的模型。通过过氧中间体从二铁（II）前体到（FeFeIV）-Fe-III物种

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The diiron(II) complex [Fe-2(mu-OH)(2)(6-Me-3-TPA)(2)]-(ClO4)(2) has recently been synthesized as a model of nonheme diiron proteins. This compound reacts with dioxygen at low temperatures to generate a diiron(III) peroxo species followed by a high-valent Fe(III)Fe(IV) complex. [References: 29]

机译：最近已经合成了二铁（II）复合物[Fe-2（mu-OH）（2）（6-Me-3-TPA）（2）-（ClO4）（2）作为非血红素二铁蛋白的模型。该化合物在低温下与双氧反应生成过氧化二铁（III），然后生成高价的Fe（III）Fe（IV）配合物。 [参考：29]

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics 》 |2000年第11期| 共2页
作者
MacMurdo VL.; Que L.; Zheng H.;
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正文语种 eng
中图分类化学 ;
关键词
Fe-2(mu-o)(2) diamond core; Methane monooxygenase; Oxo proteins; Molecular-structures; Ferrous complexes; Dioxygen binding; Enzymes; Ligand; Mechanism; Sites;

机译：Fe-2（mu-o）（2）金刚石核;甲烷单加氧酶;Oxo蛋白;分子结构;亚铁配合物;双氧结合;酶;配体;机制;位点;

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1. Model for the cofactor formation reaction of E-coli ribonucleotide reductase. From a diiron(II) precursor to an (FeFeIV)-Fe-III species via a peroxo intermediate [J] . MacMurdo VL., Que L., Zheng H. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2000 ,第11期

机译：大肠杆菌核糖核苷酸还原酶辅因子形成反应的模型。通过过氧中间体从二铁（II）前体到（FeFeIV）-Fe-III物种
2. Model for the cofactor formation reaction of E-coli ribonucleotide reductase. From a diiron(II) precursor to an (FeFeIV)-Fe-III species via a peroxo intermediate [J] . MacMurdo VL., Que L., Zheng H. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2000 ,第11期

机译：大肠杆菌核糖核苷酸还原酶辅因子形成反应的模型。通过过氧中间体从二铁（II）前体到（FeFeIV）-Fe-III物种
3. Mu-1,2-peroxo)diiron(III/III) complex as a precursor to the diiron(III/IV) intermediate X in the assembly of the iron-radical cofactor of ribonucleotide reductase from mouse. [J] . Yun D, Garcia-Serres R, Chicalese BM, Biochemistry . 2007 ,第7期

机译：Mu-1,2-peroxo）diiron（III / III）配合物，是小鼠中核糖核苷酸还原酶的铁自由基辅因子组装中diiron（III / IV）中间体X的前体。
4. Anodic Deposition of a Mixed Co/Cu Precursor for the Preparation of Cu_xCo_(3-x)O_4 Coatings for the Oxygen Evolution Reaction:Effect of Added Cu(II) Species on Nucleation and Growth of an Hydrous CoO(OH) Film [C] . N.Fradette, B.Marsan, D.L.Piron The Meeting of the Electrochemical Society . 2000

机译：混合Co / Cu前体的阳极沉积用于制备Cu_xco_（3-x）O_4涂层的氧气进化反应：添加的Cu（II）物种对含水CoO（OH）膜的成核和生长的作用
5. Model complexes as probes of heme and nonheme enzymatic mechanisms: (1) Ferric peroxo porphyrin complexes as mimics of P450 enzymes using the ferric peroxo species as an active oxidant. (2) Strongly oxidizing iron (III) complexes as models of the active site intermediates of lipoxygenase. [D] . Wertz, Diana L. 1999

机译：将复合物建模为血红素和非血红素酶机制的探针：（1）使用过氧化铁物种作为活性氧化剂，将过氧化铁卟啉复合物模拟为P450酶。（2）强氧化铁（III）络合物作为脂氧合酶活性位点中间体的模型。
6. Factors Influencing Conversion Kinetics of Triply-Bridged (μ-η1:η1-Peroxo)Diiron(III) Intermediates to Doubly-Bridged (μ-η1:η1-Peroxo)Diiron(III) Intermediates [O] . Jonathan R. Frisch, Ryan McDonnell, Elena V. Rybak-Akimova, -1

机译：二铁（III）中间体以双桥联（μ-η1：η1过氧）二铁（Ⅲ）中间体：影响三重桥联（η1过氧μ-η1）的转化动力学因素
7. (m-1, 2-Peroxo)diiron(III/III) Complex as a Precursor to the Diiron(III/IV) Intermediate X in the Assembly of the Iron-Radical Cofactor of Ribonucleotide Reductase from Mouse [O] . -1

机译：（M-1,2-杂环）DiOron（III / III）作为DiOron（III / IV）中间体X的前体，其在小鼠的核糖核苷酸还原酶的铁 - 自由基辅因子组合中中间体X

Model for the cofactor formation reaction of E-coli ribonucleotide reductase. From a diiron(II) precursor to an (FeFeIV)-Fe-III species via a peroxo intermediate

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