Direct synthesis of a bis(pyrazolyl)boratocopper(I) complex: Synthesis and characterization of [H2B(3,5-(CF3)(2)Pz)(2)]Cu(PPh3)(2) displaying an unusual coordination mode for a poly(pyrazolyl)borate ligand

摘要

The synthesis of [H2B (3,5-(CF3)(2)PZ)(2)]Cu(PPh3)(2) from (PPh3)(2) CuBH4 and 3,5-(CF3)2PzH and the solid state structure featuring an essentially monodentate coordination of a bis(pyrazolyl)borate ligand are described. [References: 18]