Tmtacn,tacn,and triammine complexes of (#eta#~6-arene)O_s~II:Syntheses,characterizations,and photosubstitution reactiosn(tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane;tacn=1,4,7-triazacyclononane)

Renyi Wang; Todd A.Eberspacher; Tai Hasegawa; Victor Day; David Day; Henry Taube

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Tmtacn,tacn,and triammine complexes of (#eta#~6-arene)O_s~II:Syntheses,characterizations,and photosubstitution reactiosn(tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane;tacn=1,4,7-triazacyclononane)

【24h】

Tmtacn,tacn,and triammine complexes of (#eta#~6-arene)O_s~II:Syntheses,characterizations,and photosubstitution reactiosn(tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane;tacn=1,4,7-triazacyclononane)

机译：（＃eta＃〜6-芳烃基）O_s〜II的Tmtacn，tacn和三胺配合物：合成，表征和光解反应（tmtacn = 1,4,7-三甲基-1,4,7-三氮杂环壬烷; tacn = 1 ，4,7-三氮杂环壬烷）

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A series of (#eta#~6-arene)Os~(II) complexes containing the saturated nitrogen honor ligands tmtacn,tacn,and NH_3 are prepared and characterized.The electrochemical propertes and photochemical reactios of thes ecomplexes are studied,and the solid-state structures for [(#eta#~6-p-cymene)Os(tacn)](PF_6)_2(1) and [(#eta#~6-p-cymene)Os(tacn)](PF_6)_2(2) are determined.Single-crystal X-ray data:1,orthorhombic,space group Pbca-D_(2h)~(15) (No.61),with a=14.716(3)A,b=17.844(3)A,c=18.350(4)A,V=4819(2) A~3,and Z=8;2,monooclinic,space group X2-C_2~3 (No.5),with a=17.322(4)A,b-10.481(3)A,c=15.409(4)A,#beta#=98.72deg,V-2701(1) A~3,and Z=4.

机译：制备并表征了一系列含饱和氮素配体tmtacn，tacn和NH_3的（＃eta＃〜6-芳烃基）Os（II）配合物。研究了这些配合物的电化学性质和光化学反应，得到了固体。 [（＃eta＃〜6-p-cymene）Os（tacn）]（PF_6）_2（1）和[（＃eta＃〜6-p-cymene）Os（tacn）]（PF_6）_2的状态结构确定（2）。单晶X射线数据：1，斜方晶，空间群Pbca-D_（2h）〜（15）（No.61），a = 14.716（3）A，b = 17.844（3 A，c = 18.350（4）A，V = 4819（2）A〜3，Z = 8; 2，单斜，空间群X2-C_2〜3（No.5），a = 17.322（4） A，b-10.481（3）A，c = 15.409（4）A，＃beta＃= 98.72deg，V-2701（1）A〜3，Z = 4。

著录项

来源
《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2001年第4期|共8页
作者
Renyi Wang; Todd A.Eberspacher; Tai Hasegawa; Victor Day; David Day; Henry Taube;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Tmtacn,tacn,and triammine complexes of (#eta#~6-arene)O_s~II:Syntheses,characterizations,and photosubstitution reactiosn(tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane;tacn=1,4,7-triazacyclononane) [J] . Renyi Wang, Todd A.Eberspacher, Tai Hasegawa, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第4期

机译：（＃eta＃〜6-芳烃基）O_s〜II的Tmtacn，tacn和三胺配合物：合成，表征和光解反应（tmtacn = 1,4,7-三甲基-1,4,7-三氮杂环壬烷; tacn = 1 ，4,7-三氮杂环壬烷）
2. Syntheses, characterizations, and reactivities of new 1,4,7-trimethyl-l,4, 7-triazacyclononane (Me 3 tacn) molybdenum and tungsten complexes [J] . Zhang Cai-Xia, Fang Duo-Wen, Wang Jun-Ling, Inorganica Chimica Acta . 2020,第1期

机译：新的1,4,7-三甲基-1,4,7-三氮杂萘醌（ME 3 TACN）钼和钨复合物的合成，表征和反应性
3. Dinuclear 1,4,7-triazacyclononane (tacn) complexes of cobalt(III) with amido and tacn bridges. Synthesis, characterization and reversible acid-accelerated bridge cleavage [J] . Andersen P, Glerup J, Gumm A, Dalton transactions: An international journal of inorganic chemistry . 2004,第18期

机译：钴（III）与酰胺和tacn桥的双核1,4,7-三氮杂环壬烷（tacn）络合物。合成，表征和可逆的酸加速桥裂解
4. Synthesis of a tetranuclear vanadium cubane-type cluster protected by Co(III) complexes with 1,4,7-triazacyclononane ligands [C] . Keisuke Kawamoto, Sugiarto, Yoshihito Hayashi 日本化学会春季年会講演予稿集 . 2018

机译：由CO（III）配合物保护的四核钒嵌合型簇与1,4,7-三氮杂环烷配体保护
5. Physical and chemical investigations of iron complexes with 1,4,7-trimethyl-1,4,7-triazacyclononane and [2.2.2.2.3]adamanzane. [D] . Blakesley, David William. 2001

机译：与1,4,7-三甲基-1,4,7-三氮杂环壬烷和[2.2.2.2.3]金刚烷的铁配合物的物理和化学研究。
6. The Zn(II)-1,4,7-Trimethyl-1,4,7-Triazacyclononane Complex: A Monometallic Catalyst Active in Two Protonation States [O] . Marta Diez-Castellnou, Giovanni Salassa, Fabrizio Mancin, 1970

机译：Zn（II）-1,4,7-三甲基-1,4,7-三氮杂环壬烷络合物：在两个质子化状态下具有活性的单金属催化剂
7. Synthesis and Characterization of a Dinuclear Chromium(III) Complex with Two Amido Bridges and One Hydroxo Bridge. Crystal Structure of Na(tacn)Cr(mu-NH2)2(mu-OH)Cr(tacn)(ClO4)4.H2O (tacn = 1,4,7-Triazacyclononane). [O] . Peter Andersen, Hanne Bengaard, Jørgen Glerup, 1998

机译：二核桥梁和一个羟基桥的二核铬（III）配合物的合成与表征。 Na （TACN）Cr（MU-NH2）2（MU-OH）Cr（TACN）（CLO4）4.H2O（TACN = 1,4,7-三缩植Clonane）的晶体结构。

Tmtacn,tacn,and triammine complexes of (#eta#~6-arene)O_s~II:Syntheses,characterizations,and photosubstitution reactiosn(tmtacn=1,4,7-trimethyl-1,4,7-triazacyclononane;tacn=1,4,7-triazacyclononane)

摘要

著录项

相似文献

相关主题

期刊订阅