Synthesis, Structural Characterization, and Photophysics of Dinuclear Gold(II) Compelxes [{Au(dppn)Br}_2](PF_6)_2 and [{Au(dppn)I}_2(PF_6)_2 with an Unsupported Au~(II)-Au~(II) Bond

Vivian Wing-Wah Yam; Chi-Kwan Li; Chui-Ling Chan; Kung-Kai Cheung

首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >Synthesis, Structural Characterization, and Photophysics of Dinuclear Gold(II) Compelxes [{Au(dppn)Br}_2](PF_6)_2 and [{Au(dppn)I}_2(PF_6)_2 with an Unsupported Au~(II)-Au~(II) Bond

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Synthesis, Structural Characterization, and Photophysics of Dinuclear Gold(II) Compelxes [{Au(dppn)Br}_2](PF_6)_2 and [{Au(dppn)I}_2(PF_6)_2 with an Unsupported Au~(II)-Au~(II) Bond

机译：具有不受支持的Au〜（II）的双核金（II）配合物[{Au（dppn）Br} _2]（PF_6）_2和[{Au（dppn）I} _2（PF_6）_2）的合成，结构表征和光物理性质-Au〜（II）债券

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A series of novel dinuclear gold(II) compelxes having an unsupported Au(II)-Au(II) bond with well-defined oxidation state at the gold center were synthesized. Red shifts in both the low-energy absorption and emission bands were observed upon increasing the donor ability of the coordianted halogen atoms.

机译：合成了一系列新颖的双核金（II）复合物，这些复合物具有在金中心明确定义的氧化态的无支撑的Au（II）-Au（II）键。在增加配位卤素原子的供体能力时，在低能吸收带和发射带中都观察到红移。

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《Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics》 |2001年第27期|共5页
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Vivian Wing-Wah Yam; Chi-Kwan Li; Chui-Ling Chan; Kung-Kai Cheung;
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Synthesis, Structural Characterization, and Photophysics of Dinuclear Gold(II) Compelxes [{Au(dppn)Br}_2](PF_6)_2 and [{Au(dppn)I}_2(PF_6)_2 with an Unsupported Au~(II)-Au~(II) Bond

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