Dye-Sensitized Solar Cell Based on Polyaniline/Multiwalled Carbon Nanotubes Counter Electrode

摘要

This work presented the successful fabrication of dye-sensitized solar cell using polyaniline base (EB), multiwalled carbon nanotubes (MWCNTs), organic dye (rhodamine B or riboflavin), zinc oxide (ZnO), and indium tin oxide (ITO). The electrical properties of the resultant devices were investigated by measuring the current density voltage (J-V), capacitance voltage (C-V), and impedance measurements under both dark and illuminated conditions. The photovoltaic cell characteristics, that is, open circuit voltage (V_(oc)), short circuit current density (J_(sc)), and energy conversion efficiency (η), were evaluated under illumination and were found to be 0.48 mA/cm~2, 400 mV, and 0.224%, respectively, for ITO/EB-MWCNTs/ZnO-rhodamine B/ITO heterostructure. Using impedance spectra, it was found that the series resistances of this type of solar cell are 62 and 60 Ω under darkness and illumination, respectively.