Synthesis and structure of a tin(II) phosphatooxalate, Sn-2(PO4)[C2O4](0.5) containing one-dimensional tin phosphate chains

摘要

The synthesis and structure of a nem tin(HT) phosphato-oxalate, Sn-2(PO4)[C2O4](0.5), containing one-dimensional tin phosphate chains are presented. The structure comprises a network of pyramidal SnO3, truncated square, pyramidal SnO4, and tetrahedral PO4 moieties which gives rise to one-dimensional tin phosphate chains separated by the oxalate groups. These linkages create Sn-O-Sn bonding in this structure. (C) 1998 Academic Press. [References: 19]