An IR Study of the Polyethylene and Primary Aromatic Amines lnteraction

摘要

The interaction of 4,4'-diamino-3,3'-dichlorophenylmethane and polyethylene with increased amount of unsaturated fragments in polymer chains and also with its low molecular analog-decene-1 was investigated.It was shown that the interaction occurs by both addition to the double bonds and by formation of H-complexes with participation of amino groups and oxo-functions formed in the course of polymer thermo-oxidation.The conclusion is confirmed by the results of quantum-chemical calculations of model systems.