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Synthesis and Evaluation of Detergent/Dispersant Additives from Polyisobutylene Succinimides

机译:聚异丁烯琥珀酰亚胺的洗涤剂/分散剂的合成与评价

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摘要

Lube oil additives are essential for all types of lubricating oils;they are added either to give the oils new properties as detergency and oxidation stability or to improve such properties as pour point and viscosity index.They are added at varying proportions to meet the performance requirements.The present work is concerned with studying of detergent/dispersant type additives based on synthesized polyisobutylene succinic anhydride (PIBSA) and its aminated compounds (PIBSA) with different types of polyethylene polyamine such as ethylene diamine,diethylene Triamine,Triethylene tetramine,and tetraethylene pentamine.Different types of polyisobutylene succinimides were reacted with dodecylphenol and formaldehyde to prepare different type of Mannish bases.The efficiency of the prepared compounds as antioxidants and detergents/dispersants was investigated.It was found that compound D_1 (Mannich base IV) is the best antioxidant additive for lube oil,and all the prepared compounds have excellent dispersancy power.
机译:润滑油添加剂对于所有类型的润滑油都是必不可少的;添加润滑油既可以赋予润滑油新的去污力和氧化稳定性,也可以改善其倾点和粘度指数等性能,并以不同的比例添加以满足性能要求目前的工作涉及基于合成的聚异丁烯琥珀酸酐(PIBSA)及其胺化化合物(PIBSA)与不同类型的聚乙烯多胺(如乙二胺,二亚乙基三胺,三亚乙基四胺和四亚乙基五胺)的洗涤剂/分散剂型添加剂的研究。将不同类型的聚异丁烯琥珀酰亚胺与十二烷基苯酚和甲醛反应制得不同类型的曼尼什碱,研究了制备的化合物作为抗氧化剂和清净剂/分散剂的效率,发现化合物D_1(曼尼希碱IV)是最好的抗氧化剂。润滑油添加剂,所有制备的化合物均具有excell ent分散能力。

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