Kinetic Features of Radical Dissociation in Filled Acetyl Cellulose

摘要

The kinetic patterns of the diphthaloyl ethane dissociation in acetyl cellulose at 320-370 K with the formation of stable radicals have been considered as a function of the aerosil content. The profound filler effect was found to be upon the temperature dependence of the radical yield. Kinetic parameters of the radical dissociation are determined by the structural modifications of the polymer under shaping of interfaces.